wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

Assertion :Aldol condensation is usually carried out in dilute solution of a strong base. Reason: Concentrated solution of strong base involves Cannizzaro reaction.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
Assertion is correct but Reason is incorrect
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
D
Both Assertion and Reason are incorrect
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution

The correct option is C Assertion is correct but Reason is incorrect
In aldol condensation, an enol or an enolate ion reacts with a carbonyl compound to form a β-hydroxyaldehyde or β-hydroxyketone (an aldol reaction), concentration of the base is not predominately used to break the C=O.

So in aldol reaction base is used to form enolate means to abstract acidic hydrogen from alpha position. Alpha hydrogens are more acidic so a weaker base can abstract it.

Hence it is carried out in dilute solution of base.

50% concentrated NaOH solution is generally used in Cannizaro reaction as it is used for aldehydes which do not have α-H. (There are a few exceptions though)

Option C is correct.

flag
Suggest Corrections
thumbs-up
0
similar_icon
Similar questions
View More
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Other Important Reactions
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon