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Question

Assertion :Alkyl isocyanide can be prepared by carbyl amine reaction. Because Reason: Ethyl amine when heated with chloroform in presence of alcoholic KOH, alkanamide is formed.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is C Assertion is correct but Reason is incorrect
Alkyl isocyanide can be prepared by carbylamine reaction. In the carbylamine reaction (also known as the Hofmann isocyanide synthesis) potassium hydroxide reacts with chloroform to produce dichlorocarbene. This then converts primary amines to isocyanides. As it is only effective for primary amines, it is used as a chemical test for their presence.

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