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Question

Assertion :All halogens undergo disproportionation reaction in alkaline medium. Reason: All halogens exhibit variable oxidation states.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is D Both Assertion and Reason are incorrect
Cl2 , Br2 and I2 undergo disproportionation reaction whereas fluorine shows departure being the most electronegative element. Fluorine cannot exhibit positive oxidation state and hence does not show disproportionation tendency.
Fluorine can exhibit only -1 oxidation state.

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