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Question

Assertion :An aqueous solution of sodium thiosulphate on acidification turns milky white. Reason: Colloidal sulphur is formed during acidification of an aqueous solution thiosulphate.


Read the above assertion and reason and choose the correct option regarding it.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Option (A) is correct.
A mild reducing agent is used for sensitized silver bromide.
The unreacted is treated with sodium thiosulphate (hypo) to give a soluble complex.
AgBr+2Na2S2O3Na3[Ag(S2O3)2]+NaBr
An aqueous solution of sodium thiosulphate on acidification turns milky white because colloidal sulphur is formed.
Na2S2O3+2HCl2NaCl+H2O+SO2+S

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