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Question

Assertion :An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature. Reason: With decrease in temperature, randomness (entropy) decrease.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
A process is spontaneous at high temperatures and nonspontaneous at low temperatures. Both ΔH and ΔS are negative. This condition describes an exothermic process that involves a decrease in system entropy. In this case, ΔG will be negative if the magnitude of the TΔS term is less than ΔH.

Option B is correct.

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