Assertion: Aryl halides undergo electrophilic substitution more readily than benzene. Reason: Aryl halide gives a mixture of o−,p− products when they undergo electrophilic substitution.
A
Assertion and Reason are correct and Reason is the correct explanation of Assertion
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B
Assertion and Reason are correct but Reason is not the correct explanation of Assertion
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C
Assertion is true and Reason is false
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D
Assertion is false and Reason is true
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Solution
The correct option is D Assertion is false and Reason is true X- (halogen group)has two effects−I & +M. Due to −I effect of X- group, it reduces electron density of benzene so halobenzene is less reactive than benzene for electrophilic substitution reaction. But due to +M effect, it is ortho, para directing and in halobenzene further substitution takes place at ortho and para positions.