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Question

Assertion: Aryl iodides can be prepared by reaction of arenes with iodine in the presence of an oxidising agent.

Reason: Oxidising agent oxidises I2 into HI

A

Assertion and reason both are correct statements but reason is not correct explanation of assertion.

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B
Assertion and reason both are wrong statements.
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C
Assertion and reason both are correct and reason is the correct explanation of assertion.
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D
Assertion is correct but reason is wrong statement
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E
Assertion is wrong but reason is correct statement.
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Solution

The correct option is D Assertion is correct but reason is wrong statement
Assertion:

Alkyl iodide can be prepared by reaction of arenes with iodine in the presence of an oxidising agent.

Halogenation reaction


So, the assertion is correct.

Reason:

HI convert into I2 by the oxidizing agent such as HIO3, although, HI can convert aryl halides into arenes.

5HI+HIO33H2O+3I2

So, the reason is incorrect.

Conclusion: Assertion is correct but reason is wrong statement.

Hence the correct option is c.

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