The correct option is A If both the assertion and reason are true and reason is the correct explanation of assertion.
NH4Cl(aq)→NH+4(aq)+Cl−(aq)
NH+4 ions formed, undergo hydrolysis with water to form NH4OH and H+ ions. NH4OH is a weak base and thus remains almost unionised in solution. As a result, [H+] ions increase in solution, making the solution acidic.