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Question

Assertion :Assertion : If reaction quotient, Qc for a particular reaction is greater than Kc the reaction will proceed in the direction of reactants. Reason: Reason : Reaction quotient is defined in the same way as the equilibrium constant Kc except that the concentrations in Qc are not necessarily equilibrium values.

A
If both the assertion and reason are true and reason is the correct explanation of assertion.
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B
If both the assertion and reason are true but reason is not the correct explanation of assertion.
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C
If assertion is true but reason is false.
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D
If both assertion and reason are false.
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Solution

The correct option is B If both the assertion and reason are true but reason is not the correct explanation of assertion.
(I) For equilibrium KC=QC so, if QC>KC then QC will decrease as the reaction progress until it becomes equal to KC, As a result of this the reaction will progress in backward direction (i.e in direction of reactants).
(II) Reaction quotient QC is defined in same way as the equilibrium constant KC except the concentrations taken are not necessarily the equilibrium value.

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