Assertion :Assertion : The acidic strength of haloacids increases in the order: HI<< HBr << HCl << HF . Reason: Reason : Strength of acid HA depends only on the electronegativity difference between H and A.
A
If both the assertion and reason are true and reason is the correct explanation of assertion.
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B
If both the assertion and reason are true but reason is not the correct explanation of assertion.
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C
If assertion is true but reason is false
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D
If both assertion and reason are false.
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Solution
The correct option is D If both assertion and reason are false. The correct order of acidic strength is HF<<HCl<<HBr<<HI. While comparing elements in the same group of the periodic table, H-A bond strength is a more important factor in determining acidity than its polar nature. As the size of A increases down the group, H-A bond strength decreases and so the acid strength increases.