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Question

Assertion :CaF2 is soluble in water but CaI2 is not soluble in water. Reason: CaF2 is more ionic than CaI2.


Read the above assertion and reason and choose the correct option regarding it.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Assertion is incorrect but Reason is correct.
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Solution

The correct option is D Assertion is incorrect but Reason is correct.
Option (D) is correct.
Fluoride is very electronegative, and thus the bonding forces between Ca2+ and each fluoride anions are very strong, they are tightly held together in the crystal form. A few water molecules do not have enough strength to get in between and dissolve it. Thus, CaF2 is insoluble in water but more ionic, having high lattice energy due to small size of F.

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