The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
Carbohydrates are hydrocarbons which are polyhydroxy aldehydes and ketones having C: H: O ratio as 1:2:1, as in glucose which has molecular formula C6H12O6. All carbohydrates, however, do not show this ratio, for example, rhamnose is a crystalline sugar, C6H12O5. It is an important component of the polysaccharides of plant cell walls. When this sugar reacts with water one oxygen is replaced by the hydrogen atom and thus becomes deoxy sugar. Thus, the correct answer is option B.