Assertion :Diamond is thermodynamically less stable than its allotrope graphite. Reason: Molar entropy of graphite is greater than that of diamond under similar conditions.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Assertion is incorrect but Reason is correct

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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Diamond has a compact cubic crystal structure,where as graphite has a smoother hexagonal layer like structure.
Diamond is stable than graphite due to their structural differences but not for their molar entropies.
So, both Assertion and Reason are true,but Reason is not the correct explanation.

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Similar questions

In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct answer out of the following choices.

(a) Assertion and Reason both are correct statements an Reason is correct explanation for Assertion.

(b) Assertion and Reason both are correct satements but Reason is not correct explanation for Assertion.

(d) Assertion is wrong statement but Reason is correct statement.

Assertion (A) Graphite is a good conductor of electricity however diamond belongs to the category of insulators.

Reason (R) Graphite is soft in nature on the other hand diamond is very hard and brittle.

Q. Assertion
If BOD level of water in reservoir is less than 5 ppm it is not polluted.

Reason
High biological oxygen demand means low activity of bacteria in water.

Q. ASSERTION:

Δ_{f} H^{o}

for white phosphorus has been taken to be zero, whereas black phosphorus is the most stable allotrope of phosphorus and this is the only exception.

REASON:
The reference standard state of white phosphorus is taken despite the fact that this form is not the most stable allotrope but simply the most reproducible form of phosphorus.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion

Lithium sulphate does not form alums.

Reason

$L i^{+}$ is too small to form a stable lattice required for double-salt/alum formation.

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