Assertion : Diamond is thermodynamically less stable than its allotrope graphite Reason : Molar entropy of graphite is greater than that of diamond under similar conditions.
A
Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
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B
Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
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C
Statement-1 is True, Statement-2 is False
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D
Statement-1 is False, Statement-2 is True
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Solution
The correct option is B Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 C(diamond)→C(graphite)ΔHr=−ve ΔGrxn=ΔHr−TΔS ΔS is +ve ∴ΔGr=−ve⇒ spontaneoues reaction ∴C(graphite) is more stable.