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Question

Assertion :Dipole moment of o-dichloro benzene is larger than the theoretical value. Reason: Due to dipole-dipole repulsion of two Cl-atoms in ortho position bond angle is greater than 60o.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is D Assertion is incorrect but Reason is correct
Dipole moment of o-dichloro benzene is smaller than the theoretical value.
Due to dipole-dipole repulsion of two Cl-atoms in ortho position bond angle is greater than 60.

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