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Question

Assertion :Dumas method is more applicable to nitrogen-containing organic, compounds than Kjeldahl's method Reason: Kjeldahl's method does not give satisfactory results for compounds in which N is linked to O atom

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

Kjeldahl's method is a faster method than Dumas' method. However, this method is used only for those organic compounds that are converted quantitatively to ammonium sulphate on heating strongly with concentrated sulphuric acid.

It involves CuSO4 or Hg as a catalyst.

Kjeldahl's method cannot be used for the organic compounds,
  • Containing nitrogen in the ring, e.g., pyridine, quinoline etc.
  • Containing nitro (NO2) and diazo (-N = N-) groups.

Whereas duma's method can be applied to the for the nitrous compound

Hence, the correct option is B

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