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Standard X

Chemistry

Introduction to Alcohols

Assertion :Du...

Question

Assertion :During $H V Z$ reaction of a carboxylic acid, an alpha hydrogen of acid is replaced by halogen. Reason: $R C H X C O X$ formed in the intermediate step supplies X to $R C H_{2} C O O H$ .

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Assertion is incorrect but Reason is correct

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Solution

The correct option is C Assertion is correct but Reason is incorrect
Mechanism:

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Similar questions

Q. Assertion: The impurities such as

{SiO}_{2}

present in iron ore is removed by

{CaCO}_{3}

.

Reason:

CaO

formed by decomposition of

{CaCO}_{3}

reacts with

{SiO}_{2}

to form slag.

Assertion – The non-fusible impurities present in iron ore are removed by $C a C O_{3}$ .

Reason: $C a C O_{3}$ which decomposes into $C a O$ and $C O_{2}$ . The $C a O$ formed reacts with $S i O_{2}$ to remove silica

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) Ethanol is a weaker acid than phenol.
Reason (R) Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.
Reason (R) Addition of water in acidic medium proceeds through the formation of primary carbocation.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

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Assertion :During HVZ reaction of a carboxylic acid, an alpha hydrogen of acid is replaced by halogen. Reason: RCHXCOX formed in the intermediate step supplies X to RCH2COOH.

The correct option is C Assertion is correct but Reason is incorrectMechanism:

Assertion :During $H V Z$ reaction of a carboxylic acid, an alpha hydrogen of acid is replaced by halogen. Reason: $R C H X C O X$ formed in the intermediate step supplies X to $R C H_{2} C O O H$ .

The correct option is C Assertion is correct but Reason is incorrect
Mechanism: