Stability of Fully Filled and Half Filled Orbitals
Assertion : ...
Question
Assertion :Fe+3 ion is more stable than Fe+2. Reason: Fe+3 ion has more number of unpaired electrons than Fe+2.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Assertion is incorrect but Reason is correct.
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Solution
The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion. Fe+3[Ar]3d5 unpaired electrons 5 Fe+2[Ar]3d6 unpaired electrons 4 Fe+3 is more stable because of the half filled orbitals (d5) which posses a symmetrical distribution of electrons and allow maximum number of exchanges.