Assertion :For A + 2B $\to$ C (rate = K[A] $^{1}$ [B] $^{0}$ ), the half life time of reaction is only defined when concentration of A and B are in stoichometric ratio. Reason: For above reaction, half life of reaction is directly proportional to concentration of A and not to concentration of B due to its zero order.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Assertion is incorrect but Reason is correct

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Solution

The correct option is C Assertion is correct but Reason is incorrect
If the concentration of B is much lower than the stoichiometric concentration, then there will not be sufficient quantity of B to react with A and the half life period cannot be defined. Hence, the assertion is correct.
Since the reaction is first order with respect to A, the half life is independent of the concentration of A. Hence, the reason is not correct.

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Similar questions

Assertion (A) Order of the reaction can be zero or fractional.

Reason (R) We cannot determine order from balanced chemical equation.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) The enthalpy of reaction remains constant in the presence of a catalyst.

Reason (R) A catalyst participating in the reaction forms different activated complex and lowers down the activation energy but the difference in enrgy of reactant and product remains the same.

Q. Assertion : Two electrons of helium atom are placed in only one shell but three electrons of lithium need two shells.
Reason: A shell can have maximum

{2n}^{2}

electrons.

Assertion (A) All collision of reactant molecules lead to product formation.

Reason (R) Only those collisions in which molecules have correct orientation and sufficient kinetic energy lead to compound formation.

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