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Question

Assertion :For PCl5(g)PCl3(g)+Cl2(g). If more Cl2 is added the equilibrium will shift in backward direction hence, equilibrium constant will decrease. Reason: Addition of inert gas to the equilibrium mixture at constant volume, does not alter the equilibrium

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is D Assertion is incorrect but Reason is correct
For PCl5(g)PCl3(g)+Cl2(g). If more Cl2 is added the equilibrium will shift in backward direction but, equilibrium constant will not be affected.
Addition of inert gas to the equilibrium mixture at constant volume, does not alter the equilibrium.
Assertion is incorrect but Reason is correct.
Note: In the above chemical reaction, Cl2 is one of the products. It is not an inert gas. When Cl2is added, more and more Cl2 will react with PCl3 to form PCl5

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