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Question

Assertion :Formation of a pi bond restricts the rotation of the bond. Reason: While rotating the double bond, the perpendicular laterally overlapped p orbitals will reach non overlapping position.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Formation of a pi bond restricts the rotation of the bond.This is because the pi bonds formed is in mutually perpendicular direction to that of sigma bond. since it is formed due to lateral overlapping which will be destroyed in rotating the bond, hence the pi bond will break.
Hence, the rotation of pi bond is not possible as it will break on rotating leading to only sigma bond between the atoms.

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