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Question

Assertion :Formic acid reduces Tollen's reagent. Reason: Compounds containing CHO group reduce Tollen's reagent.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Tollens’ test, also known as silver-mirror test, is a qualitative laboratory test used to distinguish between an aldehyde and a ketone. It exploits the fact that aldehydes are readily oxidized , whereas ketones are not.

HCOOH acts as a reducing agent because it can be easily oxidised to CO2 and H2O and hence reduces Tollen's reagent.

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