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Question

Assertion :H2S is more acidic than H2O. Reason: HS bond is more polar than HO bond.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
The S-H bond is weaker than the O-H bond, meaning that H2S more easily donates a proton and is, therefore, more acidic.
Water is amphoteric; it can act both as a proton donor (acid property) and as a proton acceptor (base property).
Because of this, oxygen holds onto the hydrogen better than sulfur. So H2S is a stronger acid because sulfur can't hang onto that hydrogen as well as oxygen can. Remember, to be a good acid, you need to be able to lose your hydrogen atoms.
Thus, option A is correct.

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