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Question

Assertion :Hydrides of N, O and F have lower boiling points than the hydrides of their subsequent group members. Reason: Boiling point depends upon the molecular mass only.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is D Both Assertion and Reason are incorrect
Apart from molecular mass, boiling point also depends upon inter molecular forces. Due to higher electronegativity of N, O and F, the magnitude of hydrogen bonding in their hydrides will be quite high. Hence their boiling points will be higher than the hyrides of their subsequent group members.

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