Assertion: In crystal lattice, size of the cation is larger in a tetrahedral hole than in an octahedral hole.
Reason: The cations occupy more space than anions in crystal packing.
A
Both the assertion and reason is correct
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B
Assertion is correct but the reason is incorrect
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C
Assertion is incorrect but the reason is correct
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D
Both the assertion and reason are incorrect
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Solution
The correct option is D Both the assertion and reason are incorrect In crystal lattice tetrahedral void is smaller than the octahedral void as Radius of tetrahedral void =0.225 RRadius of octahedral void =0.414 R
Anions are larger in size than cations so anions occupy more space.