Assertion :In hexagonal close packing, voids are in between the three touching spheres whose centres lie at the corners of an equilateral triangle. Reason: In hexagonal close packing, voids are called square voids.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is C Assertion is correct but Reason is incorrect In hexagonal close packing (hcp) and cubic close packing (ccp), each sphere of second layer touches with three spheres of first layer. Thus, they leave a small space in between which is known as tetrahedral site or interstices. The vacant space between four touching spheres is called as tetrahedral void. Since a sphere touches three spheres in the below layer and three spheres in the above layer, there are two tetrahedral sites associated with one sphere. It may by noted that a tetrahedral site does not mean that the site is tetrahedral in geometry but it means that this site is surrounded by four spheres and the centres of these four spheres lie at the apices of a regular tetrahedron.