Assertion :In rock salt structure, all the octahedral voids in the close packing of anions are occupied by cations. Reason: In rock salt structure, the distance of closest approach between two anions is equal to half the face diagonal of the unit cell.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Assertion is incorrect but Reason is correct

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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
In rock salt structure, all the octahedral voids in the close packing of anions are occupied by cations.
In rock salt structure, the distance of closest approach between two anions is equal to half the face diagonal of the unit cell i.e. $\frac{\sqrt{2} a}{2} = (r_{+} {+ r}_{-})$

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Similar questions

In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct answer out of the following choices.

(a) Assertion and Reason both are correct statements an Reason is correct explanation for Assertion.

(b) Assertion and Reason both are correct satements but Reason is not correct explanation for Assertion.

(d) Assertion is wrong statement but Reason is correct statement.

Assertion (A) The packing efficiency is maximum for the fcc structure.

Reason (R) The coordination number is 12 in fcc structures.

In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct answer out of the following choices.

(a) Assertion and Reason both are correct statements and Reason is correct explanation for Assertion.

(b) Assertion and Reason both are correct satements but Reason is not correct explanation for Assertion.

(d) Assertion is wrong statement but Reason is correct statement.

Assertion (A) Total number of octahedral voids present in unit cell of cubic close packing including the one that is present at the body centre, is four.

Reason (R) Besides the body centre there is one octahedral void present at the centre of each of the six faces of the unit cell and each of which is shared between two adjacent unit cells.

Assertion

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Reason

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