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Question

Assertion :In sodium chloride crystal, the Na+ ion occupies the octahedral void while Cl ions occupy the vertices of octahedron. Reason: The radius ratio, rNa+rCl lies between 0.414 to 0.732.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
In sodium chloride crystal, the Na+ ion occupies the octahedral void with coordination no. of Na+ ion 6 while Cl ions occupy the vertices of octahedron.
The radius ratio lies between 0.414 to 0.732 for coordination no. 6.
Hence, A is the correct option.

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