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Question

Assertion :In the extraction of Ag, complex Na[Ag(CN)2] is reacted with Zn. Reason: Zn is d-block transition metal.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect and Reason is correct
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Solution

The correct option is C Assertion is correct but Reason is incorrect
Treatment of the cyanide compound of silver with zinc gives displacement reaction in which silver is obtained.
2[Ag(CN)2]+Zn[Zn(CN)4]2+2Ag.
This displacement is possible because zinc is more active than silver.
Zn is d-block metal but not transition metal.

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