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Question

Assertion :In the titration of Na2CO3 with HCl using methyl orange indicator, the volume required at the equivalence point is twice that of the acid required using phenolphthalein indicator. Reason: 2 mol of HCl am required for complete neutralization of one mol of Na2CO3.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Equivalents of Na2CO3= Equivalents of HCl
So, in the titration of Na2CO3 with HCl using methyl orange indicator, the volume required at the equivalence point is twice that of the acid required using phenolphthalein indicator.
12 mol of Na2CO3=11 mol of HCl
1 mol of Na2CO3=2 mol of HCl

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