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Byju's Answer
Standard XII
Chemistry
Stability of Fully Filled and Half Filled Orbitals
Assertion:Low...
Question
Assertion:Low spin tetrahedral complexes are rarely observed. Reason:The orbital splitting energies are not sufficiently large to force pairing.
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Q.
Assertion :In tetrahedral complexes low spin configurations are rarely observed. Reason:
Δ
t
=
(
4
9
)
Δ
0
Q.
Why are low spin tetrahedral complexes rarely observed?
Q.
Assertion :Inner orbital complexes are low spin complexes. Reason: In low spin complexes, inner d-orbital (3d) is used in hybridisation.
Q.
(a) What type of isomerism is shown by the complex
[
C
o
(
N
H
3
)
5
(
S
C
N
)
]
2
+
?
(b) Why is
[
N
i
C
l
4
]
2
+
paramagnetic while
[
N
i
(
C
N
)
4
]
2
−
is diamagnetic?
(Atomic number of
N
i
=
28
)
(c) Why are low spin tetrahedral complexes rarely observed?
Q.
(a) What type of isomerism is shown by the complex
[
C
o
(
N
H
3
)
5
(
S
C
N
)
]
2
+
?
(b) Why is
[
N
i
C
l
4
]
2
−
paramagnetic while
[
N
i
(
C
N
)
4
]
2
−
is diamagnetic? (Atomic number of Ni = 28)
(c) Why are low spin tetrahedral complexes rarely observed?
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