Assertion :Malonic acid (HOOC−CH2−COOH) does not form cyclic anhydride on heating. Reason: It is like β- keto acid, on heating it prefer to decarboxylate.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion β− keto acids decarboxylate very easily the reaction is promoted by tautomerism and mesomerism. Malonic acid is a β- keto acid so it prefers to decarboxylate forming acetic acid