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Question

Assertion :Many endothermic reactions that are not spontaneous at room temperature become spontaneous at high temperature. Reason: Entropy of the system increases with increase in temperature.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
As we know,
ΔG=ΔHTΔS
and free energy change should be negative for spontaneous reaction so
for endothermic reaction as temp. increases
TΔS>ΔHandΔG=ve
So,
On increasing temperature, the endothermic reaction becomes spontaneous.

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