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Standard XII
Chemistry
Factors Affected by Hydrogen Bonding
Assertion:o-n...
Question
Assertion:o-nitrophenol is a weaker acid than p-nitrophenol. Reason: Intramolecular hydrogen bonding makes ortho isomer weaker than para isomer.
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Q.
Assertion (A): P-Nitrophenol is stronger acid than O-nitrophenol.
Reason (R): Intramolecular hydrogen bonding makes ortho - isomer weaker acid than para - isomer.
Q.
Assertion :p-Nitrophenol is a stronger acid than o-nitrophenol. Reason: Intramolecular hydrogen bonding makes the o-isomer weaker than the p-isomer
Q.
Assertion :p- Nitrophenol is a stronger acid than o-nitrophenol. Reason: Intramolecular H-bond makes o-isomer weaker than p-isomer.
Q.
Ortho-nitrophenol is steam volatile whereas para-nitrophenol is not. This is due to
1.
Intramolecular hydrogen bonding present in ortho-nitrophenol
2.
Intermolecular hydrogen bonding present in para-nitrophenol
3.
Intramolecular hydrogen bonding present in para-nitrophenol
4.
Inter-molecular hydrogen bonding present in ortho-nitrophenol.
Q.
Assertion (A) : Ortho and para nitrophenols can be separated by steam distillation.
Reason (R) : Ortho nitrophenol exhibits intramolecular hydrogen bonding while para nitrophenol exists as associated molecules.
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