Assertion: On addition of NH4Cl to NH4OH,pH decreases but remains greater than 7. Reason: Addition of ⊝NH4 ion decreases ionisation of NH4, thus [OH] decreases and also pH decreases.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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E
Both Assertion and Reason are incorrect
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Solution
The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion Adding a common ion prevents the weak acid or weak base from ionizing as much as it would without the added common ion. The common ion effect suppresses the ionization of a weak acid by adding more of an ion that is a product of this equilibrium.
So addition of CH3COONa to CH3COOH increases the pH of solution but addition of NH4Cl to NH4OH decreases the pH of solution.