Assertion: pH of an aqueous solution decreases from 4 to 2.
Reason: The acidic character of the solution increases.
Both assertion and reason are correct and the reason is the correct explanation of the assertion.
Explanation for assertion statement:
Explanation for the reason statement:
The pH of a solution decreases when the acidity of the solution increases.
Thus, both assertion and reason are correct and the reason is the correct explanation for the assertion.
Hence, the correct option is (A).