Assertion :Real gases behave as ideal gases most closely at low pressure and high temperature. Reason: Intermolecular force between ideal gas molecules is assumed to be zero.
The ideal gas law can be derived from the kinetic theory of gases and relies on the assumptions that (1) the gas consists of a large number of molecules, which are in random motion and obey Newton's laws of motion; (2) the volume of the molecules is negligibly small compared to the volume occupied by the gas; and (3) no forces act on the molecules except during elastic collisions of negligible duration.
Although no gas has these properties, the behaviour of real gases is described quite closely by the ideal gas law at sufficiently high temperatures and low pressures, when relatively large distances between molecules and their high speeds overcome any interaction.