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Question

Assertion: σ is strong while π is a weak bond.


Reason : Atoms rotate freely about π bond.


A
Both assertion and reason are true, and reason is not the true
explanation of the assertion.
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B
Both assertion and reason are true, but reason is the true
explanation of the assertion.
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C
Assertion is true, but reason is false
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D
Both assertion and reason are false.
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Solution

The correct option is D Assertion is true, but reason is false
σ bond is stronger than π bond because in σ bond the overlap is axial while in π bond. It is lateral.

Due to the lateral overlap in π bond atoms cannot rotate freely in π bond.
So, assertion is true and reason is false.

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