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Question

Assertion :Silicon is not expected to form an allotrope with graphite like structures. Reason: There is feasibility to ppπ bond in silicon.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Both Assertion and Reason are incorrect.
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
(i) There is feasibility to ppπ bond in silicon(ii) π bonding between oxygen and silicon involving p and d orbitals decreases availability of lone-pairs of electrons on oxygen.
(ii) Contrary to (CH3)2O,(SiH3)2O does not form addition compound with BF3.
SO Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Hence option A is correct.

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