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Question

Assertion :Sodium chloride is added during electrolysis of fused anhydrous magnesium chloride. Reason: Anhydrous magnesium chloride is obtained by heating hydrated magnesium chloride, MgCl2.6H2O.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is C Assertion is correct but Reason is incorrect
Sodium chloride is added during electrolysis of fused anhydrous magnesium chloride. As It lowers the fusion temperature of MgCl2 and provide conductivity to the electrolyte.

And also, on direct heating of MgCl2.6H2O, anhydrous MgCl2 is not obtained due to its hydrolysis so hydrated MgCl2 is heated in vacuum in current of dry HCl gas and MgCl2 is formed.

Option C is correct.

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