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Question

Assertion: Sodium chloride is added to precipitate soap after saponification.


Reason: Hydrolysis of esters of long chain fatty acids by alkali produces soap in colloidal form.

Choose the correct option.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Both Assertion and Reason are incorrect
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D
Assertion is correct but Reason is incorrect
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E
Assertion is incorrect but Reason is correct
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Sodium chloride is added to precipitate soap after saponification.
Salt is added to decrease the solubility of soap and it help precipitate out (or salt out) from the aqueous solution.

Hydrolysis of esters of long chain fatty acids by alkali produces soap in colloidal form.
Thus, when oils and fats (glycerides) are heated with a solution of sodium hydroxide, they break down to sodium salt of the respective fatty acid (called soap) and glycerol The process is called saponification.

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

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