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Question

Assertion :Solubility of AgCl in NH3(aq.) is greater than in pure water. Reason: When AgCl dissolve in NH3(aq.), complex ion formation Ag(NH3)+2 takes place and solubility equilibria of AgCl shifted in forward direction.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Solubility of AgCl in NH3(aq.) is greater than in pure water because when AgCl dissolve in NH3(aq.) it will form complex ion with Ag+ and formation of Ag(NH3)+2 takes place and because of this solubility equilibria of AgCl shifted in forward direction and it dissolve more with respect to pure water.

Ag++2NH3(aq)[Ag(NH3)2]+

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