Assertion :Statement − 1 : Coordination isomerism occurs when both cation and anion are complex. Reason: Statement − 2 : The complexes with coordination number 6 form octahedral complexes involving either sp3d2 or d2sp3 hybridization.
A
Statement − 1 is true, Statement − 2 is true and Statement − 2 is correct explanation for Statement − 1.
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B
Statement − 1 is true, Statement − 2 is true and Statement − 2 is NOT the correct explanation for Statement − 1.
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C
Statement − 1 is true, Statement − 2 is false.
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D
Statement − 1 is false, Statement − 2 is true.
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Solution
The correct option is B Statement − 1 is true, Statement − 2 is true and Statement − 2 is NOT the correct explanation for Statement − 1. The complexes with coordination number 6 form octahedral complexes and to form complex they need six orbital and for this, they form complex either by d2sp3orsp3d2 hybridization.