Assertion :Statement-I : The standard free energy changes of all sponatneously occuring reactions are negative. Because Reason: Statement-II: The standard free energies of the elements in their standard states at 1bar and 298K are taken as zero.
Read the above statements and choose the correct option regarding it.
A
Statement-I is true, Statement-II is true ; Statement-II is correct explanation for Statement-I.
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B
Statement-I is true, Statement-II is true ; Statement-II is not a correct explanation for Statement-I.
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C
Statement-I is true, Statement-II is false.
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D
Statement-I is false, Statement-II is true.
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Solution
The correct option is B Statement-I is true, Statement-II is true ; Statement-II is not a correct explanation for Statement-I. The standard free energy changes of all spontaneously occurring reactions are negative. When a process is spontaneous, the total entropy (sys+surr) increases and the Gibbs free energy decreases. The standard free energies of the elements in their standard states at 1bar and 298K are taken as zero. Hence, statement-I is true, Statement-II is true ; Statement-II is not a correct explanation for Statement-I.