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Question

Assertion :Tert-Butoxide is a stronger base than OH or C2H5O ion but is a much poorer nucleophile.
Because Reason: A negatively charged ions is always more powerful nucleophile than its conjugate acid.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Tert-Butoxide (CH3)3CO is a stronger base than OH or C2H5O ion due to presence of +I inductive effect or electron releasing methyl groups. But it is a much poorer nucleophile as t-butoxide a bulky base and steric hindrance do not allow the reaction with ease.

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