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Question

Assertion :tert-butyl alcohol undergoes acid catalysed dehydration readily than propanol. Reason: 3° alcohols do not give Victor-Meyer’s test

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Alcohol which forms the more stable carbocation undergoes dehydration more readily. Since tert-butyl alcohol forms more stable tert-butyl cation, therefore,it undergoes dehydration most readily than propanol.
1 and 2 alcohols give Victor-Meyer’s test but not 3o alcohol.
Hence both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

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