Assertion: The basicity of orthophosphorous acid is two. Reason: In ortho-phosphorous acids, two replaceable hydrogen atoms are present.
A
Both Assertion and Reason are true and Reason is the correct explanation of Assertion
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B
Both Assertion and Reason are true and Reason is not the correct explanation of Assertion
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C
Assertion is true and Reason is false
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D
Assertion is false but Reason is true
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Solution
The correct option is A Both Assertion and Reason are true and Reason is the correct explanation of Assertion In an acid the number of hydrogen atoms which can be repalced by a base is called basicity of the acid.
The structure of orthophosphorus acid is given above.
It contains two -OH group from which hydrogen can be removed. Hence its basicity us two.
Note - (-H) do not contribute to basicity because it can't be removed.