Assertion :The correct IUPAC name of H3C−CH(CH3)−CH2−CH(CH3)−CH2−CH3 is 2,4-dimethylhexane not 3,5-dimethylhexane. Reason: In case the parent chain has two or more substitution numbering must be done in such a way that the sum of the position number of the locants on the parent chain is the lowest possible.