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Question

Assertion :The correct IUPAC name of H3CCH(CH3)CH2CH(CH3)CH2CH3 is 2,4-dimethylhexane not 3,5-dimethylhexane. Reason: In case the parent chain has two or more substitution numbering must be done in such a way that the sum of the position number of the locants on the parent chain is the lowest possible.

A
If both Assertion and Reason are correct and Reason is the correct explanation of Assertion.
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B
If both Assertion and Reason are correct but Reason is not the correct explanation of Assertion.
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C
If Assertion is correct but Reason is incorrect.
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D
If Assertion is incorrect but Reason is correct.
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Solution

The correct option is A If both Assertion and Reason are correct and Reason is the correct explanation of Assertion.
The correct IUPAC name for the compound is 2,4-dimethylhexane, not 3,5-dimethylhexane. In this case, the parent chain has two substituents, thus numbering is done in such a way that the sum of the locants on the parent chain is the lowest possible, which is 2 + 4 = 6 and not 3 + 5 = 8.

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