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Question

Assertion :The dco in bridging carbonyl group is longer than that of terminal carbonyl group. Reason: With an increase in the extent of synergic bonding, the CO bond length increases.


Read the above assertion and reason and choose the correct option regarding it.

A
Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
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B
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1
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C
Statement-1 is true, statement-2 is false.
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D
Statement-1 is false, statement-2 is true.
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Solution

The correct option is A Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
The dco in bridging carbonyl group is longer than that of terminal carbonyl group.because of With increase in extent of synergic bonding, the C---O bond length increases.
In bridging carbonyl group, extent of MCO bonding increases due to involvement of two metals for one CO group.
Hence option A is correct.

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