Assertion :The equilibrium (given below) attained in a closed vessel remains unaltered by the addition of CaCO3(s)
CaCO3(s)⇌CaO(s)+CO2(g)↑ Reason: Heterogenous reaction is unaffected by solid and liquid.
If reactants and products are found in two or more phases, the equilibria describing them is called heterogeneous equilibrium. In heterogeneous solutions, the molarity of solids and liquids remain constant throughout the reaction, which means their value can be denoted as 1.
Thus equilibrium (given below) attained in a closed vessel remains unaltered by the addition of CaCO3(s) because heterogenous reaction is unaffected by solid and liquid.
CaCO3(s)⇌CaO(s)+CO2(g)↑
Option A is correct.